2012 / 05

ORIGINAL RESEARCH

Synthesis and antioxidative properties of some fullerene C60 derivatives

Ioutsi VA1, Sokolov SA2,3, Semivrazhskaya OO, Apenova MG, Belov NM, Kovalev SV3, Shevchenko VE3, Negrebetsky VV1
About authors

1 Department of Chemistry, Medical Faculty,
Pirogov Russian National Research Medical University, Moscow, Russia

2 Department of Physical Chemistry, Chemical Faculty,
Lomonosov Moscow State University, Moscow, Russia

3 N. N. Blokhin Russian Cancer Research Center, Moscow, Russia

Correspondence should be addressed: Vitaly Ioutsi
ul. Ostrovityanova, d. 1, Moscow, Russia, 117997; ur.liam@gro_kilativ

Received: 2012-05-23 Accepted: 2012-09-19 Published online: 2017-01-05
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Synthesis and investigation of the antioxidative properties of four new fullerene C60 derivatives are reported. Two new synthetic procedures of the fulleropyrrolidine derivatives preparation were developed. All structures were confirmed by means of nuclear magnetic resonance spectroscopy and infrared spectroscopy, mass-spectrometry with laser desorption/ionization and high-resolution mass-spectrometry. Antioxidative properties were investigated by determination of peroxide number using the standard procedure.

Keywords: antioxidant activity, fulleropyrrolidines, cycloaddition

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